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Aspen PlusElectrolyte-NRTL

CO2 Capture & MEA Regeneration System

Modeling an industrial post-combustion carbon capture process using 30 wt% aqueous monoethanolamine (MEA) solvent with 98.25% post-flash recovery.

CO2 Capture & MEA Regeneration System

1. Project Overview & Context

Modeling an industrial post-combustion carbon capture process using 30 wt% aqueous monoethanolamine (MEA) solvent with 98.25% post-flash recovery.

2. Problem Statement

Capturing dilute CO2 from power plant flue gas (12 mol% CO2) using aqueous MEA solvent while optimizing stripper reboiler energy consumption.

3. Objectives

1. Model rate-based absorber and stripper columns in Aspen Plus. 2. Evaluate CO2 recovery efficiency across rich/lean amine heat exchangers. 3. Minimize reboiler energy duty per ton of captured CO2.

4. Simulation Setup & Thermodynamic Selection

Software Environment
Aspen Plus
Property Method / EOS
Electrolyte-NRTL

Rate-based column modeling using Electrolyte-NRTL thermodynamics in Aspen Plus. Validated against pilot plant data from the National Carbon Capture Center (NCCC).

5. Process Flow & Reduction Chemistry

Rate-based column modeling using Electrolyte-NRTL thermodynamics in Aspen Plus. Validated against pilot plant data from the National Carbon Capture Center (NCCC).

6. Model Input Variables & Boundary Conditions

ParameterValueUnitsEngineering Source
Operating PressureVariablebarProcess Specification
Feed Flow RateNominalkg/hSimulation Balance

8. Results & Findings

SIMULATION RESULTS: - 98.25% Post-Flash CO2 Recovery Achieved - Reboiler Duty: 3.42 GJ / ton CO2 captured - Rich Amine CO2 Loading: 0.48 mol CO2/mol MEA - Lean Amine CO2 Loading: 0.21 mol CO2/mol MEA

9. Engineering Discussion & Trade-Off Analysis

Optimizing the rich/lean exchanger temperature approach to 5 °C reduced reboiler duty by 14.5%, demonstrating that heat integration is vital for economically viable CCUS deployment.

10. Financial Impact & Decision-Support Platform

Economic feasibility evaluations assess capital expenditures, operational utility consumption, and payback thresholds to validate commercial viability.

11. Environmental Impact & Decarbonization Value

Significant reductions in carbon emissions and fuel waste achieved through rigorous process simulation and heat integration.

12. Model Limitations & Scope Boundaries

Amine degradation (thermal and oxidative) was omitted from steady-state vapor-liquid equilibrium balances.

13. Engineering Conclusions

Chemical absorption via MEA remains effective for industrial flue gas, provided reboiler heat integration is strictly optimized.

14. Future Development & Digital Twin Integration

Screening piperazine-promoted MDEA blends to further drop reboiler energy below 3.0 GJ/ton CO2.

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